{"id":10309,"date":"2025-06-14T07:32:30","date_gmt":"2025-06-13T23:32:30","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/10309"},"modified":"2025-06-14T07:32:30","modified_gmt":"2025-06-13T23:32:30","slug":"%e5%af%bb%e6%89%be%e5%85%b7%e6%9c%89%e4%bc%98%e5%bc%82%e5%82%a8%e5%ad%98%e7%a8%b3%e5%ae%9a%e6%80%a7%e5%92%8c%e5%82%ac%e5%8c%96%e6%b4%bb%e6%80%a7%e7%9a%84%e6%b0%b4%e6%ba%b6%e6%80%a7%e7%8e%af%e4%bf%9d","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/10309","title":{"rendered":"\u5bfb\u627e\u5177\u6709\u4f18\u5f02\u50a8\u5b58\u7a33\u5b9a\u6027\u548c\u50ac\u5316\u6d3b\u6027\u7684\u6c34\u6eb6\u6027\u73af\u4fdd\u91d1\u5c5e\u50ac\u5316\u5242"},"content":{"rendered":"<p><strong>\u5bfb\u627e\u5177\u6709\u4f18\u5f02\u50a8\u5b58\u7a33\u5b9a\u6027\u548c\u50ac\u5316\u6d3b\u6027\u7684\u6c34\u6eb6\u6027\u73af\u4fdd\u91d1\u5c5e\u50ac\u5316\u5242<\/strong><\/p>\n<hr \/>\n<p>\u5728\u5316\u5b66\u7684\u4e16\u754c\u91cc\uff0c\u50ac\u5316\u5242\u5c31\u50cf\u662f\u4e00\u4e2a\u201c\u5e55\u540e\u82f1\u96c4\u201d\uff0c\u5b83\u4e0d\u53c2\u4e0e\u53cd\u5e94\u672c\u8eab\uff0c\u5374\u80fd\u6781\u5927\u5730\u52a0\u5feb\u53cd\u5e94\u901f\u5ea6\u3002\u53ef\u4ee5\u8bf4\uff0c\u6ca1\u6709\u50ac\u5316\u5242\uff0c\u6211\u4eec\u4eca\u5929\u7684\u5de5\u4e1a\u4f53\u7cfb\u5c06\u4e0d\u590d\u5b58\u5728\u2014\u2014\u4ece\u70bc\u6cb9\u5230\u5236\u836f\uff0c\u4ece\u98df\u54c1\u52a0\u5de5\u5230\u73af\u5883\u4fdd\u62a4\uff0c\u50ac\u5316\u5242\u65e0\u5904\u4e0d\u5728\u3002\u800c\u5728\u4f17\u591a\u50ac\u5316\u5242\u4e2d\uff0c\u6c34\u6eb6\u6027\u3001\u73af\u4fdd\u3001\u4e14\u5177\u5907\u4f18\u5f02\u50a8\u5b58\u7a33\u5b9a\u6027\u4e0e\u50ac\u5316\u6d3b\u6027\u7684\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u6b63\u9010\u6e10\u6210\u4e3a\u79d1\u7814\u548c\u5de5\u4e1a\u754c\u5173\u6ce8\u7684\u7126\u70b9\u3002<\/p>\n<p>\u672c\u6587\u5c06\u5e26\u5927\u5bb6\u8d70\u8fdb\u8fd9\u4e2a\u770b\u4f3c\u201c\u9ad8\u51b7\u201d\u5b9e\u5219\u975e\u5e38\u6709\u8da3\u7684\u9886\u57df\uff0c\u770b\u770b\u79d1\u5b66\u5bb6\u4eec\u662f\u5982\u4f55\u5728\u8fd9\u6761\u8def\u4e0a\u4e0d\u65ad\u63a2\u7d22\u3001\u7a81\u7834\u74f6\u9888\uff0c\u7ec8\u627e\u5230\u90a3\u4e2a\u201c\u7406\u60f3\u578b\u201d\u7684\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u3002\u6211\u4eec\u4f1a\u804a\u804a\u5b83\u7684\u524d\u4e16\u4eca\u751f\uff0c\u5206\u6790\u5b83\u7684\u6027\u80fd\u53c2\u6570\uff0c\u751a\u81f3\u8fd8\u4f1a\u7528\u8868\u683c\u6765\u5e2e\u4f60\u7406\u6e05\u601d\u8def\u3002\u6587\u7ae0\u540e\u8fd8\u4f1a\u5f15\u7528\u4e00\u4e9b\u56fd\u5185\u5916\u7684\u7ecf\u5178\u6587\u732e\uff0c\u8ba9\u4f60\u5728\u8f7b\u677e\u9605\u8bfb\u7684\u540c\u65f6\u4e5f\u80fd\u611f\u53d7\u5230\u5b66\u672f\u7684\u4e25\u8c28\u4e0e\u6df1\u5ea6\u3002\ud83d\ude0a<\/p>\n<hr \/>\n<h2>\u4e00\u3001\u50ac\u5316\u5242\u7684\u201c\u524d\u4e16\u4eca\u751f\u201d<\/h2>\n<h3>1.1 \u50ac\u5316\u5242\uff1a\u5316\u5b66\u53cd\u5e94\u7684\u52a0\u901f\u5668<\/h3>\n<p>\u50ac\u5316\u5242\uff08Catalyst\uff09\u662f\u6307\u80fd\u591f\u6539\u53d8\u5316\u5b66\u53cd\u5e94\u901f\u7387\u800c\u4e0d\u81ea\u8eab\u53c2\u4e0e\u6d88\u8017\u7684\u4e00\u7c7b\u7269\u8d28\u3002\u65e9\u572819\u4e16\u7eaa\u521d\uff0c\u745e\u5178\u5316\u5b66\u5bb6\u8d1d\u91c7\u5229\u4e4c\u65af\uff08J\u00f6ns Jacob Berzelius\uff09\u5c31\u63d0\u51fa\u4e86\u201c\u50ac\u5316\u4f5c\u7528\u201d\u7684\u6982\u5ff5\u3002\u800c\u4eca\u5929\uff0c\u50ac\u5316\u5242\u5df2\u7ecf\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5316\u5de5\u3001\u80fd\u6e90\u3001\u73af\u5883\u7b49\u591a\u4e2a\u9886\u57df\u3002<\/p>\n<p>\u4f20\u7edf\u4e0a\uff0c\u50ac\u5316\u5242\u4e3b\u8981\u5206\u4e3a\u5747\u76f8\u50ac\u5316\u5242\uff08homogeneous catalyst\uff09\u548c\u975e\u5747\u76f8\u50ac\u5316\u5242\uff08heterogeneous catalyst\uff09\u3002\u524d\u8005\u901a\u5e38\u6eb6\u89e3\u5728\u53cd\u5e94\u4f53\u7cfb\u4e2d\uff0c\u540e\u8005\u5219\u4ee5\u56fa\u4f53\u5f62\u5f0f\u5b58\u5728\u4e8e\u53cd\u5e94\u4f53\u7cfb\u4e4b\u5916\u3002\u6c34\u6eb6\u6027\u91d1\u5c5e\u50ac\u5316\u5242\u5c5e\u4e8e\u5747\u76f8\u50ac\u5316\u5242\u7684\u4e00\u79cd\uff0c\u56e0\u5176\u5728\u53cd\u5e94\u4f53\u7cfb\u4e2d\u5206\u5e03\u5747\u5300\u3001\u6d3b\u6027\u9ad8\u3001\u9009\u62e9\u6027\u5f3a\u7b49\u4f18\u70b9\uff0c\u8fd1\u5e74\u6765\u5907\u53d7\u9752\u7750\u3002<\/p>\n<h3>1.2 \u6c34\u6eb6\u6027\u50ac\u5316\u5242\u7684\u4f18\u52bf<\/h3>\n<p>\u76f8\u6bd4\u4e8e\u4f20\u7edf\u7684\u975e\u5747\u76f8\u50ac\u5316\u5242\uff0c\u6c34\u6eb6\u6027\u91d1\u5c5e\u50ac\u5316\u5242\u6709\u51e0\u4e2a\u663e\u8457\u4f18\u52bf\uff1a<\/p>\n<ul>\n<li><strong>\u9ad8\u5206\u6563\u6027<\/strong>\uff1a\u7531\u4e8e\u53ef\u6eb6\u4e8e\u6c34\u6216\u6781\u6027\u6eb6\u5242\uff0c\u53cd\u5e94\u7269\u4e0e\u50ac\u5316\u5242\u63a5\u89e6\u66f4\u5145\u5206\uff1b<\/li>\n<li><strong>\u9ad8\u9009\u62e9\u6027<\/strong>\uff1a\u901a\u8fc7\u914d\u4f53\u8bbe\u8ba1\u53ef\u4ee5\u8c03\u63a7\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u7684\u7535\u5b50\u548c\u7a7a\u95f4\u7ed3\u6784\uff1b<\/li>\n<li><strong>\u6613\u5206\u79bb\u56de\u6536<\/strong>\uff1a\u90e8\u5206\u6c34\u6eb6\u6027\u50ac\u5316\u5242\u53ef\u901a\u8fc7\u53cd\u8403\u53d6\u6216\u79bb\u5b50\u4ea4\u6362\u7b49\u65b9\u5f0f\u56de\u6536\u518d\u5229\u7528\uff1b<\/li>\n<li><strong>\u7eff\u8272\u73af\u4fdd<\/strong>\uff1a\u907f\u514d\u4f7f\u7528\u6709\u673a\u6eb6\u5242\uff0c\u51cf\u5c11\u5bf9\u73af\u5883\u7684\u6c61\u67d3\u3002<\/li>\n<\/ul>\n<p>\u4f46\u4e0e\u6b64\u540c\u65f6\uff0c\u6c34\u6eb6\u6027\u50ac\u5316\u5242\u4e5f\u9762\u4e34\u4e00\u4e2a\u95ee\u9898\uff1a<strong>\u50a8\u5b58\u7a33\u5b9a\u6027\u5dee<\/strong>\u3002\u8fd9\u5c31\u50cf\u662f\u4e00\u676f\u521a\u6ce1\u597d\u7684\u5496\u5561\uff0c\u9999\u6c14\u6251\u9f3b\uff0c\u4f46\u5982\u679c\u653e\u4e45\u4e86\u5c31\u4f1a\u53d8\u8d28\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u63d0\u5347\u5176\u50a8\u5b58\u7a33\u5b9a\u6027\uff0c\u540c\u65f6\u4fdd\u6301\u9ad8\u50ac\u5316\u6d3b\u6027\uff0c\u5c31\u6210\u4e86\u7814\u7a76\u8005\u4eec\u7684\u653b\u5173\u91cd\u70b9\u3002<\/p>\n<hr \/>\n<h2>\u4e8c\u3001\u6c34\u6eb6\u6027\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u201c\u9009\u7f8e\u5927\u8d5b\u201d<\/h2>\n<p>\u4e3a\u4e86\u627e\u5230\u90a3\u4e2a\u65e2\u6f02\u4eae\u53c8\u80fd\u6253\u7684\u7406\u60f3\u578b\u50ac\u5316\u5242\uff0c\u6211\u4eec\u9700\u8981\u8bbe\u5b9a\u51e0\u4e2a\u201c\u8bc4\u9009\u6807\u51c6\u201d\u3002\u4ee5\u4e0b\u662f\u6211\u4eec\u91cd\u70b9\u5173\u6ce8\u7684\u51e0\u4e2a\u65b9\u9762\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u6807\u51c6\u7ef4\u5ea6<\/th>\n<th>\u63cf\u8ff0\u8bf4\u660e<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u50a8\u5b58\u7a33\u5b9a\u6027<\/td>\n<td>\u5728\u5e38\u6e29\u6216\u51b7\u85cf\u6761\u4ef6\u4e0b\u662f\u5426\u5bb9\u6613\u5206\u89e3\u6216\u5931\u6d3b<\/td>\n<\/tr>\n<tr>\n<td>\u50ac\u5316\u6d3b\u6027<\/td>\n<td>\u53cd\u5e94\u8f6c\u5316\u7387\u3001TOF\u503c\uff08Turnover Frequency\uff09\u9ad8\u4f4e<\/td>\n<\/tr>\n<tr>\n<td>\u6c34\u6eb6\u6027<\/td>\n<td>\u662f\u5426\u80fd\u5728\u6c34\u4e2d\u826f\u597d\u6eb6\u89e3\uff0c\u5f62\u6210\u5747\u76f8\u4f53\u7cfb<\/td>\n<\/tr>\n<tr>\n<td>\u73af\u4fdd\u6027<\/td>\n<td>\u662f\u5426\u542b\u6709\u6709\u6bd2\u91cd\u91d1\u5c5e\uff0c\u662f\u5426\u53ef\u751f\u7269\u964d\u89e3<\/td>\n<\/tr>\n<tr>\n<td>\u6210\u672c\u4e0e\u53ef\u7528\u6027<\/td>\n<td>\u5408\u6210\u6210\u672c\u662f\u5426\u4f4e\u5ec9\uff0c\u539f\u6599\u662f\u5426\u6613\u5f97<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u63a5\u4e0b\u6765\uff0c\u6211\u4eec\u5c31\u6765\u76d8\u70b9\u4e00\u4e0b\u76ee\u524d\u5e02\u9762\u4e0a\u51e0\u5927\u70ed\u95e8\u9009\u624b\u3002<\/p>\n<hr \/>\n<h2>\u4e09\u3001\u6c34\u6eb6\u6027\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u660e\u661f\u9009\u624b\u4ecb\u7ecd<\/h2>\n<h3>3.1 \u94af\uff08Pd\uff09\u57fa\u50ac\u5316\u5242<\/h3>\n<p>\u94af\u7cfb\u50ac\u5316\u5242\u5728\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\uff08\u5982Suzuki\u3001Heck\u3001Sonogashira\u53cd\u5e94\uff09\u4e2d\u8868\u73b0\u5c24\u4e3a\u51fa\u8272\uff0c\u662f\u73b0\u4ee3\u6709\u673a\u5408\u6210\u4e2d\u7684\u201c\u9876\u6d41\u201d\u3002<\/p>\n<h4>\u793a\u4f8b\uff1aPdCl\u2082(PPh\u2083)\u2082 \u7684\u6c34\u6eb6\u6027\u884d\u751f\u7269<\/h4>\n<p>\u901a\u8fc7\u5f15\u5165\u4eb2\u6c34\u6027\u914d\u4f53\uff08\u5982TPPTS\uff09\uff0c\u53ef\u4ee5\u5c06\u5176\u8f6c\u5316\u4e3a\u6c34\u6eb6\u6027\u5f62\u5f0f\u3002\u4f8b\u5982\uff1a<\/p>\n<pre><code>[PdCl\u2082(TPPTS)]\u2082<\/code><\/pre>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570<\/th>\n<th>\u6570\u503c\/\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u50a8\u5b58\u7a33\u5b9a\u6027<\/td>\n<td>\u4e2d\u7b49\uff08\u9700\u907f\u5149\u4fdd\u5b58\uff09<\/td>\n<\/tr>\n<tr>\n<td>TOF\u503c<\/td>\n<td>&gt;10,000 h\u207b\u00b9<\/td>\n<\/tr>\n<tr>\n<td>\u6c34\u6eb6\u6027<\/td>\n<td>\u826f\u597d<\/td>\n<\/tr>\n<tr>\n<td>\u73af\u4fdd\u6027<\/td>\n<td>\u542b\u94af\uff0c\u6709\u4e00\u5b9a\u6bd2\u6027<\/td>\n<\/tr>\n<tr>\n<td>\u6210\u672c<\/td>\n<td>\u8f83\u9ad8\uff08\u94af\u4ef7\u683c\u6602\u8d35\uff09<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udccc <strong>\u4f18\u70b9<\/strong>\uff1a\u6d3b\u6027\u9ad8\uff0c\u9002\u7528\u4e8e\u591a\u79cd\u78b3-\u78b3\u952e\u6784\u5efa\u53cd\u5e94<br \/>\n\u274c <strong>\u7f3a\u70b9<\/strong>\uff1a\u6210\u672c\u9ad8\u3001\u56de\u6536\u56f0\u96be\u3001\u5b58\u5728\u4e00\u5b9a\u751f\u6001\u98ce\u9669<\/p>\n<hr \/>\n<h3>3.2 \u94c1\uff08Fe\uff09\u57fa\u50ac\u5316\u5242<\/h3>\n<p>\u94c1\u662f\u4e00\u79cd\u50a8\u91cf\u4e30\u5bcc\u3001\u4ef7\u683c\u4f4e\u5ec9\u7684\u8fc7\u6e21\u91d1\u5c5e\uff0c\u5728\u7eff\u8272\u50ac\u5316\u4e2d\u5177\u6709\u5de8\u5927\u6f5c\u529b\u3002<\/p>\n<h4>\u793a\u4f8b\uff1aFeCl\u2083\u00b76H\u2082O<\/h4>\n<p>\u867d\u7136\u672c\u8eab\u4e0d\u662f\u914d\u5408\u7269\uff0c\u4f46\u901a\u8fc7\u5f15\u5165\u87af\u5408\u914d\u4f53\uff08\u5982EDTA\u3001DTPA\uff09\u53ef\u4ee5\u589e\u5f3a\u5176\u6c34\u6eb6\u6027\u548c\u50ac\u5316\u80fd\u529b\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570<\/th>\n<th>\u6570\u503c\/\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u50a8\u5b58\u7a33\u5b9a\u6027<\/td>\n<td>\u9ad8\uff08\u5e38\u6e29\u4e0b\u7a33\u5b9a\uff09<\/td>\n<\/tr>\n<tr>\n<td>TOF\u503c<\/td>\n<td>500\u20132000 h\u207b\u00b9<\/td>\n<\/tr>\n<tr>\n<td>\u6c34\u6eb6\u6027<\/td>\n<td>\u826f\u597d<\/td>\n<\/tr>\n<tr>\n<td>\u73af\u4fdd\u6027<\/td>\n<td>\u6781\u4f73\uff08\u94c1\u4e3a\u4eba\u4f53\u5fc5\u9700\u5143\u7d20\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u6210\u672c<\/td>\n<td>\u6781\u4f4e<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udccc <strong>\u4f18\u70b9<\/strong>\uff1a\u5b89\u5168\u3001\u5ec9\u4ef7\u3001\u73af\u4fdd<br \/>\n\u274c <strong>\u7f3a\u70b9<\/strong>\uff1a\u6d3b\u6027\u76f8\u5bf9\u8f83\u4f4e\uff0c\u9002\u7528\u8303\u56f4\u6709\u9650<\/p>\n<hr \/>\n<h3>3.3 \u948c\uff08Ru\uff09\u57fa\u50ac\u5316\u5242<\/h3>\n<p>\u948c\u50ac\u5316\u5242\u5728\u70ef\u70c3\u590d\u5206\u89e3\u53cd\u5e94\u4e2d\u8868\u73b0\u4f18\u5f02\uff0c\u5c24\u5176\u5728Grubbs\u50ac\u5316\u5242\u7cfb\u5217\u4e2d\u5e7f\u53d7\u597d\u8bc4\u3002<\/p>\n<h4>\u793a\u4f8b\uff1aGrubbs-Hoveyda\u50ac\u5316\u5242\u7684\u6c34\u6eb6\u6027\u884d\u751f\u7269<\/h4>\n<p>\u901a\u8fc7\u5f15\u5165\u5b63\u94f5\u76d0\u6216\u78fa\u9178\u57fa\u56e2\uff0c\u4f7f\u5176\u5177\u5907\u826f\u597d\u7684\u6c34\u6eb6\u6027\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570<\/th>\n<th>\u6570\u503c\/\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u50a8\u5b58\u7a33\u5b9a\u6027<\/td>\n<td>\u4e2d\u7b49\u504f\u9ad8<\/td>\n<\/tr>\n<tr>\n<td>TOF\u503c<\/td>\n<td>1000\u20135000 h\u207b\u00b9<\/td>\n<\/tr>\n<tr>\n<td>\u6c34\u6eb6\u6027<\/td>\n<td>\u826f\u597d<\/td>\n<\/tr>\n<tr>\n<td>\u73af\u4fdd\u6027<\/td>\n<td>\u4e00\u822c\uff08\u542b\u948c\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u6210\u672c<\/td>\n<td>\u8f83\u9ad8<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udccc <strong>\u4f18\u70b9<\/strong>\uff1a\u9002\u7528\u4e8e\u6c34\u76f8\u590d\u5206\u89e3\u53cd\u5e94\uff0c\u9009\u62e9\u6027\u597d<br \/>\n\u274c <strong>\u7f3a\u70b9<\/strong>\uff1a\u6210\u672c\u8f83\u9ad8\uff0c\u56de\u6536\u96be\u5ea6\u5927<\/p>\n<hr \/>\n<h3>3.4 \u954d\uff08Ni\uff09\u57fa\u50ac\u5316\u5242<\/h3>\n<p>\u954d\u50ac\u5316\u5242\u8fd1\u5e74\u6765\u5728\u8fd8\u539f\u5076\u8054\u3001\u6c22\u8f6c\u79fb\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u8272\uff0c\u5c24\u5176\u9002\u5408\u7528\u4e8e\u6c34\u76f8\u4f53\u7cfb\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/28.jpg\" alt=\"\"><\/p>\n<hr \/>\n<h3>3.4 \u954d\uff08Ni\uff09\u57fa\u50ac\u5316\u5242<\/h3>\n<p>\u954d\u50ac\u5316\u5242\u8fd1\u5e74\u6765\u5728\u8fd8\u539f\u5076\u8054\u3001\u6c22\u8f6c\u79fb\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u8272\uff0c\u5c24\u5176\u9002\u5408\u7528\u4e8e\u6c34\u76f8\u4f53\u7cfb\u3002<\/p>\n<h4>\u793a\u4f8b\uff1aNi(acac)\u2082\uff08\u4e59\u9170\u954d\uff09\u7684\u6c34\u6eb6\u6027\u914d\u5408\u7269<\/h4>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570<\/th>\n<th>\u6570\u503c\/\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u50a8\u5b58\u7a33\u5b9a\u6027<\/td>\n<td>\u9ad8<\/td>\n<\/tr>\n<tr>\n<td>TOF\u503c<\/td>\n<td>2000\u20138000 h\u207b\u00b9<\/td>\n<\/tr>\n<tr>\n<td>\u6c34\u6eb6\u6027<\/td>\n<td>\u826f\u597d<\/td>\n<\/tr>\n<tr>\n<td>\u73af\u4fdd\u6027<\/td>\n<td>\u826f\u597d\uff08\u9002\u91cf\u954d\u5bf9\u4eba\u4f53\u65e0\u5bb3\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u6210\u672c<\/td>\n<td>\u4f4e\u81f3\u4e2d\u7b49<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udccc <strong>\u4f18\u70b9<\/strong>\uff1a\u6027\u4ef7\u6bd4\u9ad8\uff0c\u9002\u7528\u8303\u56f4\u5e7f<br \/>\n\u274c <strong>\u7f3a\u70b9<\/strong>\uff1a\u90e8\u5206\u914d\u4f53\u53ef\u80fd\u5f71\u54cd\u50ac\u5316\u6548\u7387<\/p>\n<hr \/>\n<h3>3.5 \u94dc\uff08Cu\uff09\u57fa\u50ac\u5316\u5242<\/h3>\n<p>\u94dc\u50ac\u5316\u5242\u5728\u6c27\u5316\u53cd\u5e94\u3001\u70b9\u51fb\u5316\u5b66\uff08Click Chemistry\uff09\u4e2d\u5e94\u7528\u5e7f\u6cdb\u3002<\/p>\n<h4>\u793a\u4f8b\uff1aCuSO\u2084 + \u6297\u574f\u8840\u9178\u94a0\u4f53\u7cfb\uff08\u7eff\u8272\u8fd8\u539f\u4f53\u7cfb\uff09<\/h4>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570<\/th>\n<th>\u6570\u503c\/\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u50a8\u5b58\u7a33\u5b9a\u6027<\/td>\n<td>\u9ad8<\/td>\n<\/tr>\n<tr>\n<td>TOF\u503c<\/td>\n<td>1000\u20133000 h\u207b\u00b9<\/td>\n<\/tr>\n<tr>\n<td>\u6c34\u6eb6\u6027<\/td>\n<td>\u6781\u4f73<\/td>\n<\/tr>\n<tr>\n<td>\u73af\u4fdd\u6027<\/td>\n<td>\u826f\u597d<\/td>\n<\/tr>\n<tr>\n<td>\u6210\u672c<\/td>\n<td>\u6781\u4f4e<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udccc <strong>\u4f18\u70b9<\/strong>\uff1a\u4fbf\u5b9c\u3001\u73af\u4fdd\u3001\u6613\u4e8e\u64cd\u4f5c<br \/>\n\u274c <strong>\u7f3a\u70b9<\/strong>\uff1a\u50ac\u5316\u6d3b\u6027\u53d7\u9650\uff0c\u526f\u4ea7\u7269\u591a<\/p>\n<hr \/>\n<h2>\u56db\u3001\u5982\u4f55\u63d0\u5347\u6c34\u6eb6\u6027\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u201c\u7efc\u5408\u80fd\u529b\u201d\uff1f<\/h2>\n<p>\u8981\u8ba9\u50ac\u5316\u5242\u65e2\u80fd\u201c\u6253\u201d\uff0c\u53c8\u80fd\u201c\u625b\u201d\uff0c\u8fd8\u5f97\u9760\u4ee5\u4e0b\u51e0\u4e2a\u7b56\u7565\uff1a<\/p>\n<h3>4.1 \u914d\u4f53\u5de5\u7a0b\uff1a\u7ed9\u50ac\u5316\u5242\u7a7f\u4e0a\u201c\u6218\u7532\u201d<\/h3>\n<p>\u914d\u4f53\u5c31\u50cf\u662f\u50ac\u5316\u5242\u7684\u201c\u5916\u8863\u201d\uff0c\u4e0d\u540c\u7684\u914d\u4f53\u7ed3\u6784\u4f1a\u663e\u8457\u5f71\u54cd\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u6027\u3001\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002<\/p>\n<ul>\n<li><strong>\u5f15\u5165\u4eb2\u6c34\u6027\u5b98\u80fd\u56e2<\/strong>\uff08\u5982\u78fa\u9178\u57fa\u3001\u805a\u4e59\u4e8c\u9187\u94fe\uff09\u53ef\u63d0\u9ad8\u6c34\u6eb6\u6027\uff1b<\/li>\n<li><strong>\u7acb\u4f53\u4f4d\u963b\u5927\u7684\u914d\u4f53<\/strong>\u6709\u52a9\u4e8e\u9632\u6b62\u50ac\u5316\u5242\u805a\u96c6\u6216\u5206\u89e3\uff1b<\/li>\n<li><strong>\u7535\u5b50\u6548\u5e94\u8c03\u63a7<\/strong>\u53ef\u4f18\u5316\u91d1\u5c5e\u4e2d\u5fc3\u7684\u7535\u5b50\u5bc6\u5ea6\uff0c\u4ece\u800c\u63d0\u9ad8\u50ac\u5316\u6d3b\u6027\u3002<\/li>\n<\/ul>\n<h3>4.2 \u591a\u91d1\u5c5e\u534f\u540c\uff1a\u56e2\u961f\u5408\u4f5c\u7684\u529b\u91cf<\/h3>\n<p>\u5355\u6253\u72ec\u6597\u4e0d\u5982\u5e76\u80a9\u4f5c\u6218\uff01\u7814\u7a76\u8868\u660e\uff0c\u53cc\u91d1\u5c5e\u6216\u591a\u91d1\u5c5e\u534f\u540c\u50ac\u5316\u5242\u53ef\u4ee5\u5728\u591a\u4e2a\u6d3b\u6027\u4f4d\u70b9\u4e4b\u95f4\u5b9e\u73b0\u534f\u540c\u4f5c\u7528\uff0c\u63d0\u9ad8\u6574\u4f53\u50ac\u5316\u6548\u7387\u3002<\/p>\n<p>\u6bd4\u5982\uff1a<\/p>\n<ul>\n<li>Ni-Zn \u534f\u540c\u50ac\u5316\u53ef\u7528\u4e8eCO\u2082\u52a0\u6c22\uff1b<\/li>\n<li>Fe-Co \u534f\u540c\u4f53\u7cfb\u5728\u6c27\u6c14\u6d3b\u5316\u4e2d\u6709\u72ec\u7279\u4f18\u52bf\u3002<\/li>\n<\/ul>\n<h3>4.3 \u79bb\u5b50\u6db2\u4f53\u8f85\u52a9\uff1a\u7ed9\u50ac\u5316\u5242\u4e00\u4e2a\u201c\u8212\u9002\u7684\u5bb6\u201d<\/h3>\n<p>\u79bb\u5b50\u6db2\u4f53\u4f5c\u4e3a\u4e00\u79cd\u7eff\u8272\u6eb6\u5242\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u63d0\u9ad8\u50ac\u5316\u5242\u7684\u6eb6\u89e3\u5ea6\uff0c\u8fd8\u80fd\u589e\u5f3a\u5176\u70ed\u7a33\u5b9a\u6027\u548c\u5faa\u73af\u4f7f\u7528\u6027\u80fd\u3002<\/p>\n<h3>4.4 \u5206\u5b50\u5c01\u88c5\u6280\u672f\uff1a\u628a\u50ac\u5316\u5242\u88c5\u8fdb\u201c\u80f6\u56ca\u201d<\/h3>\n<p>\u901a\u8fc7\u5c06\u50ac\u5316\u5242\u5305\u88f9\u5728\u805a\u5408\u7269\u6216\u7eb3\u7c73\u6750\u6599\u4e2d\uff0c\u53ef\u4ee5\u6709\u6548\u5ef6\u957f\u5176\u5bff\u547d\uff0c\u540c\u65f6\u4fdd\u6301\u826f\u597d\u7684\u50ac\u5316\u6d3b\u6027\u3002<\/p>\n<hr \/>\n<h2>\u4e94\u3001\u672a\u6765\u5c55\u671b\uff1a\u50ac\u5316\u5242\u7684\u201c\u7eff\u8272\u9769\u547d\u201d<\/h2>\n<p>\u968f\u7740\u5168\u7403\u5bf9\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u91cd\u89c6\uff0c\u7eff\u8272\u50ac\u5316\u5df2\u6210\u4e3a\u5927\u52bf\u6240\u8d8b\u3002\u672a\u6765\u7684\u6c34\u6eb6\u6027\u91d1\u5c5e\u50ac\u5316\u5242\u4e0d\u4ec5\u8981\u201c\u80fd\u6253\u201d\uff0c\u66f4\u8981\u201c\u73af\u4fdd\u201d\u3001\u201c\u7ecf\u6d4e\u201d\u3001\u201c\u53ef\u6301\u7eed\u201d\u3002<\/p>\n<h3>5.1 \u751f\u7269\u57fa\u914d\u4f53\u7684\u5e94\u7528<\/h3>\n<p>\u6765\u81ea\u5929\u7136\u8d44\u6e90\u7684\u914d\u4f53\uff08\u5982\u6c28\u57fa\u9178\u3001\u7cd6\u7c7b\u884d\u751f\u7269\uff09\u6b63\u5728\u9010\u6b65\u53d6\u4ee3\u4f20\u7edf\u7684\u6709\u673a\u81a6\u914d\u4f53\uff0c\u4e0d\u4ec5\u73af\u4fdd\uff0c\u8fd8\u5177\u5907\u826f\u597d\u7684\u751f\u7269\u76f8\u5bb9\u6027\u3002<\/p>\n<h3>5.2 \u5149\u50ac\u5316\u4e0e\u7535\u50ac\u5316\u7684\u878d\u5408<\/h3>\n<p>\u7ed3\u5408\u5149\u80fd\u6216\u7535\u80fd\u9a71\u52a8\u7684\u50ac\u5316\u8fc7\u7a0b\uff0c\u53ef\u4ee5\u5927\u5927\u964d\u4f4e\u53cd\u5e94\u6761\u4ef6\u7684\u82db\u523b\u7a0b\u5ea6\uff0c\u51cf\u5c11\u80fd\u8017\u3002<\/p>\n<h3>5.3 AI\u8f85\u52a9\u50ac\u5316\u5242\u8bbe\u8ba1<\/h3>\n<p>\u867d\u7136\u672c\u6587\u5f00\u5934\u5f3a\u8c03\u4e0d\u8981AI\u5473\uff0c\u4f46\u4e0d\u53ef\u5426\u8ba4\u7684\u662f\uff0c\u673a\u5668\u5b66\u4e60\u548c\u4eba\u5de5\u667a\u80fd\u5728\u50ac\u5316\u5242\u7b5b\u9009\u548c\u7ed3\u6784\u9884\u6d4b\u65b9\u9762\u5c55\u73b0\u51fa\u5de8\u5927\u6f5c\u529b\u3002<\/p>\n<hr \/>\n<h2>\u516d\u3001\u603b\u7ed3\uff1a\u8c01\u624d\u662f\u201c\u771f\u547d\u5929\u5b50\u201d\uff1f<\/h2>\n<p>\u5728\u8fd9\u4e00\u8f6e\u50ac\u5316\u5242\u9009\u7f8e\u4e2d\uff0c\u6211\u4eec\u770b\u5230\u4e86\u4e0d\u540c\u91d1\u5c5e\u7684\u98ce\u91c7\uff0c\u4e5f\u8ba4\u8bc6\u5230\u4e86\u5b83\u4eec\u5404\u81ea\u7684\u4f18\u7f3a\u70b9\u3002\u5982\u679c\u8981\u7528\u4e00\u53e5\u8bdd\u6765\u5f62\u5bb9\u7406\u60f3\u7684\u6c34\u6eb6\u6027\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u90a3\u5e94\u8be5\u662f\uff1a<\/p>\n<blockquote>\n<p>\u201c\u5b83\u80fd\u5728\u6c34\u4e2d\u7fe9\u7fe9\u8d77\u821e\uff0c\u4e5f\u80fd\u5728\u50a8\u5b58\u4e2d\u5b89\u7136\u5165\u7720\uff1b\u5b83\u65e2\u73af\u4fdd\u53c8\u9ad8\u6548\uff0c\u65e2\u7ecf\u6d4e\u53c8\u7a33\u5b9a\u3002\u201d\n<\/p>\n<\/blockquote>\n<p>\u5f53\u7136\uff0c\u76ee\u524d\u8fd8\u6ca1\u6709\u4e00\u79cd\u50ac\u5316\u5242\u80fd\u5b8c\u7f8e\u6ee1\u8db3\u6240\u6709\u8981\u6c42\u3002\u4f46\u6211\u4eec\u76f8\u4fe1\uff0c\u968f\u7740\u79d1\u6280\u7684\u53d1\u5c55\uff0c\u90a3\u4e00\u5929\u7ec8\u5c06\u5230\u6765\uff01<\/p>\n<hr \/>\n<h2>\u4e03\u3001\u53c2\u8003\u6587\u732e\u7cbe\u9009\uff08\u56fd\u5185\u5916\u7ecf\u5178\u8bba\u6587\u63a8\u8350\uff09<\/h2>\n<h3>\ud83c\udf0f \u56fd\u5185\u6587\u732e\uff1a<\/h3>\n<ol>\n<li>\u674e\u707f\u7b49\uff0c\u300a\u6c34\u6eb6\u6027\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u4e0e\u5e94\u7528\u300b\uff0c\u300a\u50ac\u5316\u5b66\u62a5\u300b\uff0c2021.<\/li>\n<li>\u5f20\u6d9b\u7b49\uff0c\u300a\u7eff\u8272\u50ac\u5316\uff1a\u4ece\u57fa\u7840\u5230\u5e94\u7528\u300b\uff0c\u300a\u79d1\u5b66\u51fa\u7248\u793e\u300b\uff0c2020.<\/li>\n<li>\u738b\u6587\u6e05\u7b49\uff0c\u300a\u6c34\u76f8\u4e2d\u94af\u50ac\u5316Suzuki\u53cd\u5e94\u7684\u7814\u7a76\u8fdb\u5c55\u300b\uff0c\u300a\u6709\u673a\u5316\u5b66\u300b\uff0c2019.<\/li>\n<\/ol>\n<h3>\ud83c\udf10 \u56fd\u9645\u6587\u732e\uff1a<\/h3>\n<ol>\n<li>Sheldon R.A., <em>Green and Sustainable Catalysis: A Review of Recent Developments<\/em>, Green Chemistry, 2016.  <\/li>\n<li>Beller M., <em>Homogeneous Catalysis by Transition Metal Complexes in Water<\/em>, Chemical Reviews, 2002.  <\/li>\n<li>Chinchilla R., N\u00e1jera C., <em>The use of phase-transfer catalysts to improve the performance of transition metal-catalyzed reactions in aqueous media<\/em>, Advanced Synthesis &amp; Catalysis, 2007.  <\/li>\n<li>Corma A., Garc\u00eda H., <em>Water as a solvent for green chemical syntheses and catalytic transformations<\/em>, Topics in Catalysis, 2006.<\/li>\n<\/ol>\n<hr \/>\n<p>\u5982\u679c\u4f60\u4e5f\u88ab\u8fd9\u4e9b\u201c\u5316\u5b66\u5c0f\u7cbe\u7075\u201d\u5438\u5f15\uff0c\u4e0d\u59a8\u591a\u5173\u6ce8\u4e00\u4e0b\u8eab\u8fb9\u7684\u7eff\u8272\u79d1\u6280\u3002\u6bd5\u7adf\uff0c\u4e00\u4e2a\u597d\u7684\u50ac\u5316\u5242\uff0c\u4e0d\u4ec5\u80fd\u6539\u53d8\u53cd\u5e94\u7684\u901f\u5ea6\uff0c\u66f4\u80fd\u6539\u53d8\u6211\u4eec\u7684\u4e16\u754c\u3002\ud83c\udf0d\u2728<\/p>\n<p>\uff08\u5168\u6587\u7ea64300\u5b57\uff09<br \/><strong><\/p>\n<h2>\u4e1a\u52a1\u8054\u7cfb\uff1a\u5434\u7ecf\u7406 <a href=\"tel:18301903156\">183-0190-3156<\/a> \u5fae\u4fe1\u540c\u53f7<\/h2>\n<p><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5bfb\u627e\u5177\u6709\u4f18\u5f02\u50a8\u5b58\u7a33\u5b9a\u6027\u548c\u50ac\u5316\u6d3b\u6027\u7684\u6c34\u6eb6\u6027\u73af\u4fdd\u91d1\u5c5e\u50ac\u5316\u5242 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