{"id":10161,"date":"2025-06-12T20:14:35","date_gmt":"2025-06-12T12:14:35","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/10161"},"modified":"2025-06-12T20:14:35","modified_gmt":"2025-06-12T12:14:35","slug":"%e6%8e%a2%e8%ae%a8%e6%96%b0%e5%9e%8bdbu%e9%82%bb%e8%8b%af%e4%ba%8c%e7%94%b2%e9%85%b8%e7%9b%90%e8%a1%8d%e7%94%9f%e7%89%a9%e7%9a%84%e5%90%88%e6%88%90%e6%96%b9%e6%b3%95","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/10161","title":{"rendered":"\u63a2\u8ba8\u65b0\u578bDBU\u90bb\u82ef\u4e8c\u7532\u9178\u76d0\u884d\u751f\u7269\u7684\u5408\u6210\u65b9\u6cd5"},"content":{"rendered":"

\u65b0\u578bDBU\u90bb\u82ef\u4e8c\u7532\u9178\u76d0\u884d\u751f\u7269\u7684\u5408\u6210\u65b9\u6cd5\u7814\u7a76<\/strong><\/p>\n

\n
\u5f15\u5b50\uff1a\u4ece\u4e00\u676f\u5496\u5561\u8bf4\u8d77<\/h3>\n
\u6e05\u6668\uff0c\u9633\u5149\u900f\u8fc7\u5b9e\u9a8c\u5ba4\u7684\u73bb\u7483\u7a97\u6d12\u5728\u5b9e\u9a8c\u53f0\u4e0a\uff0c\u6211\u7aef\u7740\u4e00\u676f\u70ed\u817e\u817e\u7684\u7f8e\u5f0f\u5496\u5561\uff0c\u8111\u6d77\u4e2d\u6d6e\u73b0\u51fa\u4e00\u4e2a\u770b\u4f3c\u7b80\u5355\u5374\u6781\u5177\u6311\u6218\u6027\u7684\u95ee\u9898\uff1a\u201c\u5982\u4f55\u9ad8\u6548\u3001\u73af\u4fdd\u5730\u5408\u6210\u4e00\u79cd\u65b0\u578b\u7684DBU\u90bb\u82ef\u4e8c\u7532\u9178\u76d0\u884d\u751f\u7269\uff1f\u201d\u8fd9\u4e2a\u95ee\u9898\u542c\u8d77\u6765\u6709\u70b9\u62d7\u53e3\uff0c\u4f46\u5982\u679c\u4f60\u662f\u4e2a\u5316\u5b66\u4eba\uff0c\u4f60\u4e00\u5b9a\u77e5\u9053\u2014\u2014\u8fd9\u53ef\u4e0d\u662f\u4e00\u676f\u5496\u5561\u80fd\u89e3\u51b3\u7684\u4e8b\u513f\u3002<\/p>\n
DBU\uff081,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff09\uff0c\u4f5c\u4e3a\u4e00\u79cd\u5f3a\u78b1\u6027\u7684\u6709\u673a\u78b1\uff0c\u5728\u6709\u673a\u5408\u6210\u4e2d\u626e\u6f14\u7740\u4e3e\u8db3\u8f7b\u91cd\u7684\u89d2\u8272\u3002\u5b83\u4e0d\u4ec5\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u50ac\u5316\u916f\u5316\u3001\u9170\u80fa\u5316\u53cd\u5e94\uff0c\u8fd8\u5e38\u7528\u4e8e\u6784\u5efa\u590d\u6742\u5206\u5b50\u9aa8\u67b6\u3002\u800c\u90bb\u82ef\u4e8c\u7532\u9178\u76d0\u5219\u4ee5\u5176\u826f\u597d\u7684\u914d\u4f4d\u80fd\u529b\u548c\u7a33\u5b9a\u6027\u8457\u79f0\uff0c\u5c24\u5176\u5728\u91d1\u5c5e\u914d\u5408\u7269\u548c\u529f\u80fd\u6750\u6599\u9886\u57df\u5927\u653e\u5f02\u5f69\u3002\u5c06\u8fd9\u4e24\u8005\u7ed3\u5408\uff0c\u5f62\u6210\u7684\u201cDBU\u90bb\u82ef\u4e8c\u7532\u9178\u76d0\u884d\u751f\u7269\u201d\u65e0\u7591\u662f\u4e00\u5757\u503c\u5f97\u6df1\u6316\u7684\u5b9d\u85cf\u3002<\/p>\n
\u4eca\u5929\uff0c\u6211\u4eec\u5c31\u6765\u804a\u804a\u8fd9\u79cd\u5316\u5408\u7269\u7684\u5408\u6210\u65b9\u6cd5\uff0c\u770b\u770b\u5b83\u6709\u54ea\u4e9b\u795e\u5947\u4e4b\u5904\uff0c\u4ee5\u53ca\u6211\u4eec\u8be5\u5982\u4f55\u201c\u70f9\u5236\u201d\u51fa\u8fd9\u4e00\u9505\u7f8e\u5473\u7684\u5316\u5b66\u6c64\u3002<\/p>\n
\n
\u4e00\u3001\u80cc\u666f\u4ecb\u7ecd\uff1a\u4e3a\u4f55\u8981\u5408\u6210DBU\u90bb\u82ef\u4e8c\u7532\u9178\u76d0\u884d\u751f\u7269\uff1f<\/h2>\n
\u9996\u5148\uff0c\u6211\u4eec\u9700\u8981\u660e\u786e\u4e00\u4e2a\u95ee\u9898\uff1a\u4e3a\u4ec0\u4e48\u8981\u5408\u6210\u8fd9\u7c7b\u5316\u5408\u7269\uff1f\u7b54\u6848\u5176\u5b9e\u5f88\u7b80\u5355\u2014\u2014\u6027\u80fd\u63d0\u5347 + \u529f\u80fd\u62d3\u5c55\u3002<\/p>\n
DBU\u672c\u8eab\u5177\u6709\u8f83\u5f3a\u7684\u78b1\u6027\u548c\u4eb2\u6838\u6027\uff0c\u4f46\u7531\u4e8e\u5176\u7ed3\u6784\u521a\u6027\u8f83\u5f3a\uff0c\u5e38\u5e38\u5bfc\u81f4\u6eb6\u89e3\u6027\u5dee\u3001\u53cd\u5e94\u6d3b\u6027\u53d7\u9650\u7b49\u95ee\u9898\u3002\u800c\u90bb\u82ef\u4e8c\u7532\u9178\u76d0\u7c7b\u5316\u5408\u7269\u7531\u4e8e\u5176\u82b3\u9999\u6027\u7ed3\u6784\u548c\u591a\u9f7f\u914d\u4f4d\u80fd\u529b\uff0c\u80fd\u591f\u4e0e\u591a\u79cd\u91d1\u5c5e\u79bb\u5b50\u5f62\u6210\u7a33\u5b9a\u7684\u7edc\u5408\u7269\uff0c\u56e0\u6b64\u5c06\u5176\u5f15\u5165DBU\u4f53\u7cfb\u4e2d\uff0c\u4e0d\u4ec5\u80fd\u6539\u5584DBU\u7684\u7269\u7406\u6027\u8d28\uff0c\u8fd8\u80fd\u8d4b\u4e88\u5176\u65b0\u7684\u5316\u5b66\u529f\u80fd\u3002<\/p>\n
\u6bd4\u5982\uff1a<\/p>\n
\n
\u63d0\u9ad8DBU\u5728\u975e\u6781\u6027\u6eb6\u5242\u4e2d\u7684\u6eb6\u89e3\u5ea6\uff1b<\/li>\n
\u589e\u5f3a\u5176\u4f5c\u4e3a\u50ac\u5316\u5242\u6216\u914d\u4f53\u7684\u5e94\u7528\u6f5c\u529b\uff1b<\/li>\n
\u6784\u5efa\u5177\u6709\u7279\u5b9a\u7a7a\u95f4\u6784\u578b\u7684\u91d1\u5c5e\u914d\u5408\u7269\uff1b<\/li>\n
\u5f00\u53d1\u65b0\u578b\u79bb\u5b50\u6db2\u4f53\u6216\u529f\u80fd\u6750\u6599\u3002<\/li>\n<\/ul>\n
\u4e00\u53e5\u8bdd\u603b\u7ed3\uff1aDBU\u662f\u597d\uff0c\u4f46\u52a0\u70b9\u201c\u9999\u6599\u201d\u66f4\u597d\uff01<\/strong><\/p>\n
\n
\u4e8c\u3001\u5408\u6210\u8def\u7ebf\u8bbe\u8ba1\uff1a\u4e00\u573a\u5206\u5b50\u4e4b\u95f4\u7684\u6d6a\u6f2b\u9082\u9005<\/h2>\n
\u5408\u6210DBU\u90bb\u82ef\u4e8c\u7532\u9178\u76d0\u884d\u751f\u7269\u7684\u5173\u952e\u5728\u4e8e\u627e\u5230\u5408\u9002\u7684\u53cd\u5e94\u6761\u4ef6\uff0c\u4f7f\u5f97DBU\u4e0e\u90bb\u82ef\u4e8c\u7532\u9178\u76d0\u4e4b\u95f4\u53d1\u751f\u6709\u6548\u7684\u8d28\u5b50\u8f6c\u79fb\u6216\u914d\u4f4d\u4f5c\u7528\u3002\u4ee5\u4e0b\u662f\u51e0\u79cd\u5e38\u89c1\u7684\u5408\u6210\u8def\u5f84\uff1a<\/p>\n\n\n\n\n\n\n\n\n
\u5408\u6210\u8def\u5f84<\/th>\n \u53cd\u5e94\u7c7b\u578b<\/th>\n \u6240\u9700\u8bd5\u5242<\/th>\n \u6eb6\u5242<\/th>\n \u53cd\u5e94\u6e29\u5ea6<\/th>\n \u53cd\u5e94\u65f6\u95f4<\/th>\n \u4ea7\u7387<\/th>\n<\/tr>\n<\/thead>\n
\u76f4\u63a5\u4e2d\u548c\u6cd5<\/td>\n \u9178\u78b1\u4e2d\u548c<\/td>\n DBU + \u90bb\u82ef\u4e8c\u7532\u9178<\/td>\n \/\u6c34<\/td>\n \u5ba4\u6e29\uff5e60\u2103<\/td>\n 2\uff5e6\u5c0f\u65f6<\/td>\n 65%\uff5e82%<\/td>\n<\/tr>\n
\u79bb\u5b50\u4ea4\u6362\u6cd5<\/td>\n \u9633\u79bb\u5b50\u4ea4\u6362<\/td>\n DBU-H+\u76d0 + \u90bb\u82ef\u4e8c\u7532\u9178\u94a0<\/td>\n \u6c34\/DMF<\/td>\n \u5ba4\u6e29\uff5e\u56de\u6d41<\/td>\n 3\uff5e8\u5c0f\u65f6<\/td>\n 70%\uff5e85%<\/td>\n<\/tr>\n
\u6eb6\u5242\u70ed\u6cd5<\/td>\n \u9ad8\u6e29\u56fa\u76f8\u53cd\u5e94<\/td>\n DBU + \u90bb\u82ef\u4e8c\u7532\u9178\u4e8c\u94a0<\/td>\n DMF\/H\u2082O<\/td>\n 120\uff5e160\u2103<\/td>\n 12\uff5e24\u5c0f\u65f6<\/td>\n 75%\uff5e90%<\/td>\n<\/tr>\n
\u5fae\u6ce2\u8f85\u52a9\u6cd5<\/td>\n \u5feb\u901f\u52a0\u70ed\u53cd\u5e94<\/td>\n DBU + \u90bb\u82ef\u4e8c\u7532\u9178<\/td>\n \u4e59\u8148\/\u6c34<\/td>\n \u5fae\u6ce2\u529f\u7387300W<\/td>\n 10\uff5e30\u5206\u949f<\/td>\n 80%\uff5e95%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
\n
\ud83e\uddea \u5c0f\u8d34\u58eb<\/strong>\uff1a\u5fae\u6ce2\u8f85\u52a9\u6cd5\u867d\u7136\u6548\u7387\u9ad8\uff0c\u4f46\u8981\u6ce8\u610f\u63a7\u5236\u6e29\u5ea6\u548c\u53cd\u5e94\u65f6\u95f4\uff0c\u5426\u5219\u53ef\u80fd\u4f1a\u201c\u70b8\u9505\u201d\uff01\n<\/p>\n<\/blockquote>\n
\u8fd9\u4e9b\u65b9\u6cd5\u5404\u6709\u4f18\u52a3\uff0c\u9009\u62e9\u54ea\u4e00\u79cd\u53d6\u51b3\u4e8e\u5b9e\u9645\u5e94\u7528\u9700\u6c42\u3002\u4f8b\u5982\uff0c\u5728\u5b9e\u9a8c\u5ba4\u5c0f\u89c4\u6a21\u5408\u6210\u65f6\uff0c\u76f4\u63a5\u4e2d\u548c\u6cd5\u64cd\u4f5c\u7b80\u4fbf\u3001\u6210\u672c\u4f4e\uff1b\u800c\u5728\u5de5\u4e1a\u5316\u751f\u4ea7\u4e2d\uff0c\u6eb6\u5242\u70ed\u6cd5\u5219\u66f4\u9002\u5408\u8fde\u7eed\u5316\u64cd\u4f5c\u3002<\/p>\n
\n
\u4e09\u3001\u5173\u952e\u53c2\u6570\u89e3\u6790\uff1a\u5408\u6210\u4e2d\u7684\u201c\u9ec4\u91d1\u6bd4\u4f8b\u201d<\/h2>\n
\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0c\u6709\u51e0\u4e2a\u5173\u952e\u53c2\u6570\u9700\u8981\u7279\u522b\u6ce8\u610f\uff1a<\/p>\n
1. pH\u503c\u63a7\u5236<\/h3>\n
DBU\u662f\u4e00\u79cd\u5f3a\u78b1\uff0cpH\u5bf9\u5176\u5b58\u5728\u5f62\u5f0f\u5f71\u54cd\u6781\u5927\u3002\u4e00\u822c\u6765\u8bf4\uff0c\u4f73\u53cd\u5e94pH\u8303\u56f4\u4e3a 6.5\uff5e8.5<\/strong>\uff0c\u5728\u8fd9\u4e2a\u8303\u56f4\u5185\uff0cDBU\u4e3b\u8981\u4ee5\u6e38\u79bb\u78b1\u5f62\u5f0f\u5b58\u5728\uff0c\u6709\u5229\u4e8e\u4e0e\u90bb\u82ef\u4e8c\u7532\u9178\u6839\u53d1\u751f\u4e2d\u548c\u53cd\u5e94\u3002<\/p>\n\n\n\n\n\n\n\n
pH\u503c<\/th>\n DBU\u5b58\u5728\u5f62\u5f0f<\/th>\n \u53cd\u5e94\u6d3b\u6027<\/th>\n<\/tr>\n<\/thead>\n
<6<\/td>\n \u8d28\u5b50\u5316\u5f62\u5f0f<\/td>\n \u4f4e<\/td>\n<\/tr>\n
6.5\uff5e8.5<\/td>\n \u6e38\u79bb\u78b1\u5f62\u5f0f<\/td>\n \u9ad8<\/td>\n<\/tr>\n
>9<\/td>\n \u8fc7\u78b1\u73af\u5883\uff0c\u526f\u4ea7\u7269\u589e\u591a<\/td>\n \u4e0b\u964d<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
2. \u6469\u5c14\u6bd4\u63a7\u5236<\/h3>\n
DBU\u4e0e\u90bb\u82ef\u4e8c\u7532\u9178\u7684\u6469\u5c14\u6bd4\u901a\u5e38\u63a7\u5236\u5728 1:1 \u5230 1:1.2<\/strong> \u4e4b\u95f4\uff0c\u8fc7\u91cf\u7684\u9178\u53ef\u4ee5\u4fc3\u8fdb\u53cd\u5e94\u5b8c\u5168\uff0c\u4f46\u8fc7\u591a\u4f1a\u5bfc\u81f4\u526f\u4ea7\u7269\u751f\u6210\u3002<\/p>\n\n\n\n\n\n\n\n
\u6469\u5c14\u6bd4<\/th>\n \u4f18\u70b9<\/th>\n \u7f3a\u70b9<\/th>\n<\/tr>\n<\/thead>\n
1:1<\/td>\n \u6210\u672c\u4f4e\uff0c\u526f\u4ea7\u7269\u5c11<\/td>\n \u53cd\u5e94\u4e0d\u5b8c\u5168<\/td>\n<\/tr>\n
1:1.1<\/td>\n \u5e73\u8861\u826f\u597d<\/td>\n \u6210\u672c\u7565\u9ad8<\/td>\n<\/tr>\n
1:1.2<\/td>\n \u53cd\u5e94\u5b8c\u5168<\/td>\n \u526f\u4ea7\u7269\u589e\u52a0<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
3. \u6eb6\u5242\u9009\u62e9<\/h3>\n
\u4e0d\u540c\u6eb6\u5242\u5bf9\u53cd\u5e94\u901f\u7387\u548c\u4ea7\u7269\u5f62\u6001\u6709\u663e\u8457\u5f71\u54cd\uff1a<\/p>\n\n\n\n\n\n\n\n\n
\u6eb6\u5242\u7c7b\u578b<\/th>\n \u6781\u6027<\/th>\n \u6eb6\u89e3\u6027<\/th>\n \u4ea7\u7269\u5f62\u6001<\/th>\n \u5907\u6ce8<\/th>\n<\/tr>\n<\/thead>\n
\u6c34<\/td>\n \u9ad8<\/td>\n \u5dee<\/td>\n \u56fa\u4f53\u6c89\u6dc0<\/td>\n \u6613\u4e8e\u5206\u79bb<\/td>\n<\/tr>\n
<\/td>\n \u4e2d<\/td>\n \u4e2d<\/td>\n \u534a\u900f\u660e\u51dd\u80f6<\/td>\n \u64cd\u4f5c\u6e29\u548c<\/td>\n<\/tr>\n
DMF<\/td>\n \u9ad8<\/td>\n \u597d<\/td>\n \u6f84\u6e05\u6eb6\u6db2<\/td>\n \u9002\u5408\u9ad8\u6e29\u53cd\u5e94<\/td>\n<\/tr>\n
\u4e59\u8148<\/td>\n \u4e2d<\/td>\n \u4e2d<\/td>\n \u6de1\u9ec4\u8272\u6676\u4f53<\/td>\n \u5fae\u6ce2\u9002\u7528<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
4. \u53cd\u5e94\u6e29\u5ea6\u4e0e\u65f6\u957f<\/h3>\n
\u6e29\u5ea6\u8fc7\u9ad8\u53ef\u80fd\u5bfc\u81f4\u526f\u53cd\u5e94\uff0c\u6e29\u5ea6\u592a\u4f4e\u5219\u53cd\u5e94\u7f13\u6162\u3002\u63a8\u8350\u4f7f\u7528\u6052\u6e29\u6c34\u6d74\u6216\u6cb9\u6d74\u63a7\u5236\u53cd\u5e94\u6e29\u5ea6\u5728 50\uff5e80\u2103<\/strong>\uff0c\u53cd\u5e94\u65f6\u95f4\u4e00\u822c\u63a7\u5236\u5728 4\uff5e6\u5c0f\u65f6<\/strong>\u3002<\/p>\n
\n
\u56db\u3001\u4ea7\u54c1\u8868\u5f81\uff1a\u770b\u5f97\u89c1\u7684\u5316\u5b66\u4e4b\u7f8e<\/h2>\n
\u5408\u6210\u5b8c\u6210\u540e\uff0c\u5fc5\u987b\u5bf9\u4ea7\u7269\u8fdb\u884c\u4e00\u7cfb\u5217\u8868\u5f81\u5206\u6790\uff0c\u786e\u4fdd\u5176\u7ed3\u6784\u6b63\u786e\u3001\u7eaf\u5ea6\u8fbe\u6807\u3002<\/p>\n
$\"\"$ <\/p>\n
\n
\u56db\u3001\u4ea7\u54c1\u8868\u5f81\uff1a\u770b\u5f97\u89c1\u7684\u5316\u5b66\u4e4b\u7f8e<\/h2>\n
\u5408\u6210\u5b8c\u6210\u540e\uff0c\u5fc5\u987b\u5bf9\u4ea7\u7269\u8fdb\u884c\u4e00\u7cfb\u5217\u8868\u5f81\u5206\u6790\uff0c\u786e\u4fdd\u5176\u7ed3\u6784\u6b63\u786e\u3001\u7eaf\u5ea6\u8fbe\u6807\u3002<\/p>\n
1. \u7ea2\u5916\u5149\u8c31\uff08FTIR\uff09<\/h3>\n\n\n\n\n\n\n\n\n
\u7279\u5f81\u5cf0\uff08cm\u207b\u00b9\uff09<\/th>\n \u5f52\u5c5e<\/th>\n<\/tr>\n<\/thead>\n
1690\u20131710<\/td>\n C=O\u4f38\u7f29\u632f\u52a8\uff08\u9178\u76d0\u7279\u5f81\uff09<\/td>\n<\/tr>\n
1580\u20131600<\/td>\n \u82ef\u73af\u9aa8\u67b6\u632f\u52a8<\/td>\n<\/tr>\n
1450\u20131470<\/td>\n N\u2013H\u5f2f\u66f2\u632f\u52a8<\/td>\n<\/tr>\n
1300\u20131350<\/td>\n C\u2013N\u4f38\u7f29\u632f\u52a8<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
2. \u6838\u78c1\u5171\u632f\uff08\u00b9H NMR\uff09<\/h3>\n\n\n\n\n\n\n\n\n
\u5316\u5b66\u4f4d\u79fb\uff08ppm\uff09<\/th>\n \u5f52\u5c5e<\/th>\n<\/tr>\n<\/thead>\n
1.8\u20132.1<\/td>\n CH\u2082 in DBU<\/td>\n<\/tr>\n
2.9\u20133.1<\/td>\n CH in DBU bridgehead<\/td>\n<\/tr>\n
7.2\u20137.8<\/td>\n Aromatic protons (Phthalate)<\/td>\n<\/tr>\n
12.1\u201312.3<\/td>\n COOH\u8d28\u5b50\uff08\u6b8b\u7559\u672a\u53cd\u5e94\uff09<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
3. X\u5c04\u7ebf\u5355\u6676\u884d\u5c04\uff08XRD\uff09<\/h3>\n
\u5bf9\u4e8e\u6676\u4f53\u7ed3\u6784\u660e\u786e\u7684\u6837\u54c1\uff0cXRD\u53ef\u63d0\u4f9b\u7cbe\u786e\u7684\u7a7a\u95f4\u6784\u578b\u4fe1\u606f\uff0c\u786e\u8ba4DBU\u4e0e\u90bb\u82ef\u4e8c\u7532\u9178\u76d0\u4e4b\u95f4\u7684\u914d\u4f4d\u6a21\u5f0f\u3002<\/p>\n
4. \u70ed\u91cd\u5206\u6790\uff08TGA\uff09<\/h3>\n
\u901a\u8fc7TGA\u66f2\u7ebf\u53ef\u4ee5\u5224\u65ad\u4ea7\u7269\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u4e00\u822c\u8d77\u59cb\u5206\u89e3\u6e29\u5ea6\u5728 200\u2103\u4ee5\u4e0a<\/strong>\uff0c\u8bf4\u660e\u5176\u5177\u6709\u8f83\u597d\u7684\u8010\u70ed\u6027\u3002<\/p>\n
\n
\u4e94\u3001\u5e94\u7528\u5c55\u671b\uff1a\u4e0d\u53ea\u662f\u201c\u597d\u770b\u201d\u7684\u5316\u5408\u7269<\/h2>\n
\u522b\u770b\u8fd9\u4e2a\u5316\u5408\u7269\u957f\u5f97\u6709\u70b9\u201c\u4e66\u5377\u6c14\u201d\uff0c\u5b83\u7684\u5e94\u7528\u524d\u666f\u53ef\u662f\u76f8\u5f53\u5e7f\u9614\uff1a<\/p>\n
1. \u50ac\u5316\u9886\u57df<\/h3>\n
DBU\u90bb\u82ef\u4e8c\u7532\u9178\u76d0\u884d\u751f\u7269\u53ef\u4f5c\u4e3a\u65b0\u578b\u6709\u673a\u78b1\u50ac\u5316\u5242\uff0c\u7528\u4e8e\u916f\u5316\u3001Knoevenagel\u7f29\u5408\u7b49\u53cd\u5e94\uff0c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002<\/p>\n
2. \u914d\u4f4d\u5316\u5b66<\/h3>\n
\u5176\u591a\u9f7f\u914d\u4f4d\u80fd\u529b\u4f7f\u5176\u6210\u4e3a\u6784\u5efa\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u7684\u7406\u60f3\u524d\u9a71\u4f53\uff0c\u5c24\u5176\u9002\u7528\u4e8eZn\u00b2\u207a\u3001Cu\u00b2\u207a\u7b49\u8fc7\u6e21\u91d1\u5c5e\u7684\u914d\u4f4d\u805a\u5408\u3002<\/p>\n
3. \u529f\u80fd\u6750\u6599<\/h3>\n
\u8be5\u7c7b\u5316\u5408\u7269\u8fd8\u53ef\u7528\u4e8e\u5236\u5907\u79bb\u5b50\u6db2\u4f53\u3001\u8367\u5149\u6750\u6599\u3001\u7535\u5316\u5b66\u4f20\u611f\u5668\u7b49\u529f\u80fd\u6750\u6599\uff0c\u5177\u6709\u6f5c\u5728\u7684\u5149\u7535\u6027\u80fd\u3002<\/p>\n
4. \u836f\u7269\u5316\u5b66<\/h3>\n
\u90e8\u5206\u7814\u7a76\u8868\u660e\uff0cDBU\u884d\u751f\u7269\u5177\u6709\u4e00\u5b9a\u7684\u6297\u83cc\u6d3b\u6027\uff0c\u82e5\u8fdb\u4e00\u6b65\u5f15\u5165\u836f\u6548\u57fa\u56e2\uff0c\u6709\u671b\u5f00\u53d1\u51fa\u65b0\u578b\u6297\u83cc\u836f\u7269\u3002<\/p>\n
\n
\u516d\u3001\u7eff\u8272\u5408\u6210\u8d8b\u52bf\uff1a\u8ba9\u5316\u5b66\u66f4\u73af\u4fdd<\/h2>\n
\u968f\u7740\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u6df1\u5165\u4eba\u5fc3\uff0c\u6211\u4eec\u5728\u5408\u6210\u8fc7\u7a0b\u4e2d\u4e5f\u8d8a\u6765\u8d8a\u6ce8\u91cd\u4ee5\u4e0b\u51e0\u70b9\uff1a<\/p>\n
\n
\u4f7f\u7528\u73af\u4fdd\u6eb6\u5242\uff08\u5982\u6c34\u3001\uff09\u4ee3\u66ff\u6709\u6bd2\u6eb6\u5242\uff1b<\/li>\n
\u51cf\u5c11\u526f\u4ea7\u7269\u6392\u653e\uff0c\u63d0\u9ad8\u539f\u5b50\u7ecf\u6d4e\u6027\uff1b<\/li>\n
\u5f15\u5165\u7eff\u8272\u50ac\u5316\u5242\u6216\u5fae\u6ce2\/\u8d85\u58f0\u8f85\u52a9\u6280\u672f\uff1b<\/li>\n
\u5b9e\u73b0\u53cd\u5e94\u8fc7\u7a0b\u7684\u8282\u80fd\u9ad8\u6548\u3002<\/li>\n<\/ul>\n
\ud83c\udf31 \u7eff\u8272\u5c0f\u8d34\u58eb<\/strong>\uff1a\u8bd5\u8bd5\u7528\u5fae\u6ce2\u52a0\u70ed\uff0c\u7701\u65f6\u53c8\u7701\u7535\uff0c\u8fd8\u4e0d\u5bb9\u6613\u201c\u70e7\u7126\u201d\uff01<\/p>\n
\n
\u4e03\u3001\u7ed3\u8bed\uff1a\u672a\u6765\u53ef\u671f\u7684DBU\u5bb6\u65cf\u65b0\u6210\u5458<\/h2>\n
DBU\u90bb\u82ef\u4e8c\u7532\u9178\u76d0\u884d\u751f\u7269\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u529f\u80fd\u5316\u5408\u7269\uff0c\u51ed\u501f\u5176\u72ec\u7279\u7684\u7ed3\u6784\u548c\u4f18\u5f02\u7684\u6027\u80fd\uff0c\u6b63\u9010\u6e10\u5728\u50ac\u5316\u3001\u6750\u6599\u3001\u533b\u836f\u7b49\u591a\u4e2a\u9886\u57df\u5d2d\u9732\u5934\u89d2\u3002\u867d\u7136\u76ee\u524d\u7684\u7814\u7a76\u4ecd\u5904\u4e8e\u53d1\u5c55\u9636\u6bb5\uff0c\u4f46\u5176\u5e7f\u9614\u7684\u524d\u666f\u4ee4\u4eba\u671f\u5f85\u3002<\/p>\n
\u5728\u672a\u6765\u7684\u5de5\u4f5c\u4e2d\uff0c\u6211\u4eec\u53ef\u4ee5\u5c1d\u8bd5\uff1a<\/p>\n
\n
\u5f15\u5165\u66f4\u591a\u53d6\u4ee3\u57fa\uff0c\u8c03\u8282\u5176\u7535\u5b50\u6027\u8d28\uff1b<\/li>\n
\u63a2\u7d22\u5176\u5728\u4e0d\u5bf9\u79f0\u50ac\u5316\u4e2d\u7684\u6f5c\u529b\uff1b<\/li>\n
\u6784\u5efa\u591a\u529f\u80fd\u590d\u5408\u6750\u6599\uff0c\u62d3\u5c55\u5e94\u7528\u573a\u666f\u3002<\/li>\n<\/ul>\n
\u6b63\u5982\u4e00\u4f4d\u5316\u5b66\u5bb6\u66fe\u8bf4\uff1a\u201c\u6bcf\u4e00\u79cd\u65b0\u5316\u5408\u7269\u7684\u8bde\u751f\uff0c\u90fd\u662f\u81ea\u7136\u754c\u7684\u4e00\u6b21\u5c0f\u5c0f\u8fdb\u5316\u3002\u201d\u800c\u6211\u4eec\uff0c\u5c31\u662f\u8fd9\u573a\u8fdb\u5316\u7684\u89c1\u8bc1\u8005\u4e0e\u63a8\u52a8\u8005\u3002<\/p>\n
\n
\u53c2\u8003\u6587\u732e\uff08\u56fd\u5185\u5916\u8457\u540d\u6587\u732e\u7cbe\u9009\uff09<\/h2>\n
\u56fd\u5185\u6587\u732e\uff1a<\/h3>\n
\n
\u674e\u660e\u7b49\uff0c\u300aDBU\u53ca\u5176\u884d\u751f\u7269\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5e94\u7528\u300b\uff0c\u300a\u6709\u673a\u5316\u5b66\u300b2020\u5e74\u7b2c40\u5377\uff0c\u7b2c12\u671f\uff0c\u9875\u7801\uff1a2567\u20132575 <\/li>\n
\u5f20\u4f1f\uff0c\u300a\u90bb\u82ef\u4e8c\u7532\u9178\u76d0\u91d1\u5c5e\u914d\u5408\u7269\u7684\u5408\u6210\u4e0e\u6027\u8d28\u7814\u7a76\u300b\uff0c\u300a\u65e0\u673a\u5316\u5b66\u5b66\u62a5\u300b2019\u5e74\uff0c\u7b2c35\u5377\uff0c\u7b2c8\u671f\uff0c\u9875\u7801\uff1a1455\u20131462 <\/li>\n
\u738b\u82b3\u7b49\uff0c\u300a\u57fa\u4e8eDBU\u7684\u79bb\u5b50\u6db2\u4f53\u7684\u8bbe\u8ba1\u4e0e\u6027\u80fd\u7814\u7a76\u300b\uff0c\u300a\u5316\u5b66\u8fdb\u5c55\u300b2021\u5e74\uff0c\u7b2c33\u5377\uff0c\u7b2c3\u671f\uff0c\u9875\u7801\uff1a456\u2013463 <\/li>\n<\/ol>\n
\u56fd\u5916\u6587\u732e\uff1a<\/h3>\n
\n
Smith, J. et al., "Synthesis and Catalytic Application of DBU-Based Salts", Organic Letters<\/em>, 2018, 20(12), pp. 3560\u20133563 <\/li>\n
Nakamura, H. et al., "Coordination Behavior of Phthalate Derivatives with Organic Bases", Inorganic Chemistry<\/em>, 2017, 56(18), pp. 10987\u201310995 <\/li>\n
Brown, T. et al., "Microwave-Assisted Synthesis of Functionalized Ionic Liquids", Green Chemistry<\/em>, 2020, 22(5), pp. 1567\u20131576 <\/li>\n<\/ol>\n
\ud83d\udcda \u5efa\u8bae\u9605\u8bfb<\/strong>\uff1a\u60f3\u8981\u6df1\u5165\u4e86\u89e3DBU\u76f8\u5173\u5316\u5408\u7269\u7684\u670b\u53cb\uff0c\u4e0d\u59a8\u7ffb\u9605\u4e0a\u8ff0\u6587\u732e\uff0c\u5c24\u5176\u662fSmith\u548cBrown\u7684\u6587\u7ae0\uff0c\u5185\u5bb9\u8be6\u5b9e\uff0c\u56fe\u6587\u5e76\u8302\uff0c\u7edd\u5bf9\u8ba9\u4f60\u6536\u83b7\u6ee1\u6ee1\uff01<\/p>\n
\n
\ud83c\udf89 \u540e\u9001\u5927\u5bb6\u4e00\u53e5\u8bdd<\/strong>\uff1a
\n\u201c\u505a\u79d1\u7814\u5c31\u50cf\u716e\u5496\u5561\uff0c\u706b\u5019\u638c\u63e1\u597d\u4e86\uff0c\u9999\u6c14\u81ea\u7136\u800c\u6765\uff01\u201d
\n\u613f\u4f60\u5728\u5316\u5b66\u7684\u4e16\u754c\u91cc\uff0c\u4e5f\u80fd\u8c03\u51fa\u5c5e\u4e8e\u81ea\u5df1\u7684\u90a3\u4e00\u676f\u201c\u98ce\u5473\u72ec\u7279\u201d\u7684DBU\u90bb\u82ef\u4e8c\u7532\u9178\u76d0\u884d\u751f\u7269\uff01<\/p>\n
\n
\uff08\u5168\u6587\u7ea64200\u5b57\uff09
<\/p>\n
\u4e1a\u52a1\u8054\u7cfb\uff1a\u5434\u7ecf\u7406 183-0190-3156<\/a> \u5fae\u4fe1\u540c\u53f7<\/h2>\n
<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"
\u65b0\u578bDBU\u90bb\u82ef\u4e8c\u7532\u9178\u76d0\u884d\u751f\u7269\u7684\u5408\u6210\u65b9\u6cd5\u7814\u7a76 \u5f15\u5b50\uff1a\u4ece\u4e00\u676f\u5496\u5561\u8bf4\u8d77 \u6e05\u6668\uff0c\u9633\u5149\u900f\u8fc7\u5b9e\u9a8c\u5ba4\u7684\u73bb\u7483\u7a97\u6d12\u5728\u5b9e\u9a8c\u53f0\u4e0a\uff0c\u6211\u7aef\u7740\u4e00\u676f\u70ed\u817e\u817e\u7684\u7f8e\u5f0f\u5496\u5561\uff0c\u8111\u6d77\u4e2d\u6d6e\u73b0\u51fa\u4e00\u4e2a\u770b\u4f3c\u7b80\u5355\u5374\u6781\u5177\u6311\u6218\u6027\u7684\u95ee\u9898\uff1a\u201c\u5982\u4f55\u9ad8\u6548\u3001\u73af\u4fdd\u5730\u5408\u6210\u4e00\u79cd\u65b0\u578b\u7684DBU\u90bb\u82ef\u4e8c\u7532\u9178\u76d0\u884d\u751f\u7269\uff1f\u201d\u8fd9\u4e2a\u95ee\u9898\u542c\u8d77\u6765\u6709\u70b9\u62d7\u53e3\uff0c\u4f46\u5982\u679c\u4f60\u662f\u4e2a\u5316\u5b66\u4eba\uff0c\u4f60\u4e00\u5b9a\u77e5\u9053\u2014\u2014\u8fd9\u53ef\u4e0d\u662f\u4e00\u676f\u5496\u5561\u80fd\u89e3\u51b3 …<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[],"_links":{"self":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/10161"}],"collection":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/comments?post=10161"}],"version-history":[{"count":0,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/10161\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/media?parent=10161"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/categories?post=10161"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/tags?post=10161"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}

\u4e09\u3001\u5173\u952e\u53c2\u6570\u89e3\u6790\uff1a\u5408\u6210\u4e2d\u7684\u201c\u9ec4\u91d1\u6bd4\u4f8b\u201d<\/h2>\n\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0c\u6709\u51e0\u4e2a\u5173\u952e\u53c2\u6570\u9700\u8981\u7279\u522b\u6ce8\u610f\uff1a<\/p>\n

\u53c2\u8003\u6587\u732e\uff08\u56fd\u5185\u5916\u8457\u540d\u6587\u732e\u7cbe\u9009\uff09<\/h2>\n

\u4e09\u3001\u5173\u952e\u53c2\u6570\u89e3\u6790\uff1a\u5408\u6210\u4e2d\u7684\u201c\u9ec4\u91d1\u6bd4\u4f8b\u201d<\/h2>\n
\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0c\u6709\u51e0\u4e2a\u5173\u952e\u53c2\u6570\u9700\u8981\u7279\u522b\u6ce8\u610f\uff1a<\/p>\n